Flammability and thermal degradation behavior of ethylene‐vinyl acetate/layered double hydroxides/zinc borate composites. (24th August 2016)

• Record Type: Journal Article
• Authors: Qian, Yi; Zhou, Shaojie; Chen, Xilei
• Is Part Of: Polymers for advanced technologies. Volume 28:Number 3(2017)
• Page Start: 353
• Page End: 361
• Publication Date: 2016-08-24
• Subjects: flame retardant -- Bayer red mud -- layered double hydroxides -- zinc borate -- synergistic effects; Polymers -- Periodicals; 668.9
• DOI: 10.1002/pat.3895
• Languages: English
• ISSNs: 1042-7147

Abstract

Abstract : Mg‐Al‐Fe ternary‐layered double hydroxides (LDHs) were synthesized by a calcination‐rehydration method using Bayer red mud. The products were characterized using X‐ray diffraction and thermogravimetric analysis. The flammability and thermal degradation of ethylene‐vinyl acetate/layered double hydroxides/zinc borate (EVA/LDHs/ZB) composites were studied with limiting oxygen index, UL 94, cone calorimeter test, smoke density test, and thermogravimetry‐Fourier transform infrared spectrometry. Although limiting oxygen index value of the composites decreased with increasing ZB amount, a suitable addition of ZB can apparently improve the UL 94 rating of the material. The heat release rate of the 5% ZB containing ternary composites decreased compared with the EVA/LDHs composites. It is obtained from smoke density test that ZB could help smoke suppression. The ternary composites possessed a higher thermal stability than the EVA/LDHs composites. Copyright © 2016 John Wiley & Sons, Ltd.