Direct enantioselective C-acylation for the construction of a quaternary stereocenter catalyzed by a chiral bicyclic imidazole. Issue 8 (11th January 2017)
- Record Type:
- Journal Article
- Title:
- Direct enantioselective C-acylation for the construction of a quaternary stereocenter catalyzed by a chiral bicyclic imidazole. Issue 8 (11th January 2017)
- Main Title:
- Direct enantioselective C-acylation for the construction of a quaternary stereocenter catalyzed by a chiral bicyclic imidazole
- Authors:
- Wang, Mo
Zhang, Xiao
Ling, Zheng
Zhang, Zhenfeng
Zhang, Wanbin - Abstract:
- Abstract : A direct enantioselective C -acylation of benzofuranones was developed using a chiral bicyclic imidazole catalyst and an achiral tertiary amine additive. Abstract : A direct enantioselective C -acylation of 3-substituted benzofuran-2(3 H )-ones (with up to 97% ee) was developed using a chiral bicyclic imidazole catalystOAc-DPI and an achiral tertiary amine additive DIPEA. The reaction mechanism for the direct C -acylation has been investigated using both experimental and theoretical studies.
- Is Part Of:
- Chemical communications. Volume 53:Issue 8(2017)
- Journal:
- Chemical communications
- Issue:
- Volume 53:Issue 8(2017)
- Issue Display:
- Volume 53, Issue 8 (2017)
- Year:
- 2017
- Volume:
- 53
- Issue:
- 8
- Issue Sort Value:
- 2017-0053-0008-0000
- Page Start:
- 1381
- Page End:
- 1384
- Publication Date:
- 2017-01-11
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c6cc09451a ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 2288.xml