A novel hexanuclear silver(I) complex with photoluminescence properties. (28th January 2017)

• Record Type: Journal Article
• Authors: Wu, Yining; Wu, Xuepeng; Fang, Sisi; Yang, Shuai; Li, Weitao; Wang, Huan; Yu, Xiaoxi
• Is Part Of: Polyhedron. Volume 122(2017)
• Page Start: 155
• Page End: 160
• Publication Date: 2017-01-28
• Subjects: Silver complex -- Crystal structure -- Ag–Ag interaction -- DFT calculation -- Photoluminescence; Chemistry, Inorganic -- Periodicals; Chimie inorganique -- Périodiques; Organometaalverbindingen; Anorganische chemie; 546.05
• DOI: 10.1016/j.poly.2016.08.002
• Languages: English
• ISSNs: 0277-5387

Abstract

Graphical Abstract: A hexanuclear complex of d 10 –d 10 transition metal with organosulfur ligand has been synthesized using diffusion methodology at room temperature. The DFT and photoluminescence properties of complex have been investigated, and a favorable fluorescence property was observed from the complex. Abstract: A hexanuclear complex of d 10 –d 10 transition metal with organosulfur ligand, Ag6 (py2t)6 (py2t = pyrazine-2-thiol), has been synthesized using diffusion methodology at room temperature. Crystal structure was revealed using single crystal X-ray diffraction and data indicate that the complex synthesized containing Ag–Ag bonds in the silver cluster. The density function theory (DFT) calculation was performed to investigate the molecular orbital and photoluminescence potential. The photoluminescence properties of the complex have been further investigated, and a favorable fluorescence property was observed from the complex.