Drastic solid-state luminescence color tuning of an archetypal Ir(iii) complex using polyoxometalates and its application as a vapoluminescence chemosensor. Issue 48 (29th November 2016)

• Record Type: Journal Article
• Authors: Bolle, P.; Serier-Brault, H.; Génois, R.; Faulques, E.; Boulmier, A.; Oms, O.; Lepeltier, M.; Marrot, J.; Dolbecq, A.; Mialane, P.; Dessapt, R.
• Is Part Of: Journal of materials chemistry. Volume 4:Issue 48(2016)
• Page Start: 11392
• Page End: 11395
• Publication Date: 2016-11-29
• Subjects: Materials -- Periodicals; Chemistry, Analytic -- Periodicals; Optical materials -- Research -- Periodicals; Electronics -- Materials -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c6tc04341k
• Languages: English
• ISSNs: 2050-7526

Abstract

Abstract : New assemblies based on the archetypal [Ir III (ppy)2 (bpy)] + complex and a series of polyoxometalates exhibit highly tunable phosphorescence and vapoluminescence properties for detection of volatile organic compounds. Abstract : Using a straightforward one-step synthetic procedure, the solid-state phosphorescence of the archetypal [Ir III (ppy)2 (bpy)] + complex has been successfully tuned from green to yellow, orange and red by its association with a series of polyoxometalates. Such new materials can exhibit remarkable vapoluminescence properties for the detection of volatile organic compounds (VOCs) even in the presence of moisture via a new polymorphous conversion mechanism.