Preparation and sensing properties of a nitrogen-rich ferrocene-imidazole-quinoxaline triad decorated with pyrrole rings. Issue 48 (21st November 2016)

• Record Type: Journal Article
• Authors: Alfonso, María; Tárraga, Alberto; Molina, Pedro
• Is Part Of: Dalton transactions. Volume 45:Issue 48(2016)
• Page Start: 19269
• Page End: 19276
• Publication Date: 2016-11-21
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c6dt03667h
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : The synthesis and sensing properties of the nitrogen-rich ferrocene-imidazole-quinoxaline triad1 decorated with two pyrrole rings have been described. Abstract : The synthesis and sensing properties of the nitrogen-rich ferrocene-imidazole-quinoxaline triad1 decorated with two pyrrole rings have been described. Due to its ditopic nature, this molecule behaves as an ion-pair receptor for Ni 2+ cations and AcO − anions, although no affinity for either of the discrete ions is observed. It also displays the rare property consistent with the cooperative AND recognition of ion pairs. Thus, this receptor shows an important enhancement for binding AcO − anions when it is co-bound to Hg 2+ cations, whereas no affinity for the free receptor by the anion is observed.