Fine regulation of cellulose dissolution and regeneration by low pressure CO2 in DMSO/organic base: dissolution behavior and mechanism. Issue 48 (23rd November 2016)

• Record Type: Journal Article
• Authors: Wang, Jinfang; Xue, Zhimin; Yan, Chuanyu; Li, Zhonghao; Mu, Tiancheng
• Is Part Of: Physical chemistry chemical physics. Volume 18:Issue 48(2016)
• Page Start: 32772
• Page End: 32779
• Publication Date: 2016-11-23
• Subjects: Chemistry, Physical and theoretical -- Periodicals; 541.3
• DOI: 10.1039/c6cp05541a
• Languages: English
• ISSNs: 1463-9076

Abstract

Abstract : Exploring cellulose dissolving and regenerating behavior in DMSO/organic base solvent systems with the activation of low pressure CO2 . Abstract : In this study, the fine regulation of the dissolution and regeneration of microcrystalline cellulose (MCC) using very low pressure (0–0.2 MPa) CO2 in a mixed solvent of dimethyl sulfoxide (DMSO) and 1, 8-diazabicyclo-[5.4.0]-undec-7-ene (DBU) at a very low temperature (30 °C) was achieved. The solubility of MCC in DMSO/DBU (weight ratio of DMSO W DMSO = 0.90) could reach 9.0% at 30 °C and under CO2 pressure of 0.2 MPa. A similar phenomenon was observed in the mixed solvent DMSO/1, 1, 3, 3-tetramethylguanidine (TMG). Moreover, ATR-FTIR, NMR, UV-Vis, TGA, XRD and DFT computational analyses were used to investigate the dissolution mechanism. It was concluded that in the mixed solvent (DMSO and organic base), DMSO helped to dissociate ion-pairs into free ions by balancing the concentration of free ions and the number of hydrogen bonds at W DMSO = 0.90. Interactions between CO2 and the solvent mixture were explored, and the results indicate that the optimum CO2 pressure not only promotes the formation of ionic bonds but also accelerates the formation of covalent bonds. In this way, these interactions prevent the MCC molecules from aggregating and facilitate the dissolving of MCC. This study gives a thorough insight into the dissolution mechanism and specificity of MCC in the CO2 –DMSO/organic base solvent system, which could be helpful for the utilization and transformation of cellulose.