One‐pot oxidation of aromatic and cyclic hydrocarbons using the Au (III) and Pd (II) catalyst under microwave irradiation. (4th July 2016)

• Record Type: Journal Article
• Authors: Srivastava, Manish; Srivastava, Anamika; Goyal, Ashu; Mishra, Aakanksha; Tomer, Preeti; Dwivedi, Jaya; Kishore, D.
• Is Part Of: Journal of physical organic chemistry. Volume 30:Number 2(2017)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2016-07-04
• Subjects: aromatic hydrocarbons -- in situ generated sodium ferrate -- microwave irradiation -- oxidation; Chemistry, Physical organic -- Periodicals; 547.1
• DOI: 10.1002/poc.3602
• Languages: English
• ISSNs: 0894-3230

Abstract

Abstract : We report here in highly efficient one‐pot catalytic system which utilizes in situ generated sodium ferrate for the oxidation of aromatic and cyclic hydrocarbons in the presence of Au (III) and Pd (II) metal ions catalyst under ecofriendly green synthetic method. Results of these studies revealed that Au (III) catalytic system gave higher yield as compared with Pd (II) catalytic system because of the higher electrode potential of Au(III) than Pd(II). All compounds were characterized by infrared and NMR spectral analysis. Copyright © 2016 John Wiley & Sons, Ltd. Abstract : Study the catalytic activity of Au(III) and Pd(II) catalyst for oxidation of aromatic hydrocarbon by in situ generated sodium ferrate under microwave irradiation. Au(III) catalytic system gave higher yield as compare to Pd(II) catalytic system because the electrode potential of Au(III) is higher than the electrode potential of Pd(II).