A Targeted Functional Design for Highly Efficient and Stable Cathodes for Rechargeable Li‐Ion Batteries. (19th December 2016)

• Record Type: Journal Article
• Authors: He, Guanjie; Han, Xiaoyu; Zou, Rujia; Zhao, Tingting; Weng, Zhe; Ho‐Kimura, SocMan; Lu, Yao; Wang, Hailiang; Guo, Zheng Xiao; Parkin, Ivan P.
• Is Part Of: Advanced functional materials. Volume 27:Number 4(2017)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2016-12-19
• Subjects: 3D sandwich arrays -- cathodes -- density functional theory -- in situ transmission electron microscopy -- Li‐ion batteries; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adfm.201604903
• Languages: English
• ISSNs: 1616-301X

Abstract

Abstract : Despite the great success of Li‐ion batteries (LIBs) up to now, higher demand has been raised with the emergence of the new generation electrics, such as portable devices and electrical vehicles. Even with the improvement on anodes, the cathodes with high capacity and long‐lastingness still remain a challenge. New 3D NiCo2 O4 @V2 O5 core–shell arrays (CSAs) on carbon cloth as cathodes in LIBs have been reported in this work. The nanodesigned materials realize the theoretical specific capacity of V2 O5 with high power rate based on the total mass of the framework and amount of active materials. The electrodes achieve superb cycling stability, among the most stable cathodes for LIBs ever reported. From both in situ transmission electron microscopy and quantum level calculations, the 3D NiCo2 O4 nanosheet frameworks provide high electron conductivity and the skeleton of the robust CSAs without participating in the lithiation/delithiation; the thickness of the layered V2 O5 plays a key role for Li diffusivity and the capacity contribution of electrodes. The structures herein point to new design concepts for high‐performance nanoarchitectures for LIB cathodes. Abstract : The targeted functional 3D NiCo2 O4 @V2 O5 core–shell sandwich arrays on carbon cloth for rechargeable Li‐ion battery have realized theoretical limits of specific capacity and high stability over 500 cycles. The superb performance relies on its structural nano‐architecture by separated pathways for lithiation process and conduction. The thickness of the active material is optimized and guided by theoretical study.