ChemInform Abstract: Gold(I)‐Catalyzed N‐Desulfonylative Amination versus N‐to‐O 1, 5‐Sulfonyl Migration: A Versatile Approach to 1‐Azabicycloalkanes. Issue 50 (November 2016)

• Record Type: Journal Article
• Authors: Miaskiewicz, Solene; Gaillard, Boris; Kern, Nicolas; Weibel, Jean‐Marc; Pale, Patrick; Blanc, Aurelien
• Is Part Of: ChemInform. Volume 47:Issue 50(2016)
• Page Start: no
• Page End: no
• Publication Date: 2016-11
• Subjects: fused pyrrole derivatives -- catalysis, phase‐transfer catalysis -- cascade reactions, domino reactions, tandem reactions; Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201650099
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: Various N‐sulfonyl protected 1‐azetidine‐2‐alkyn‐1‐ones are transformed in a gold(I)‐catalyzed N‐desulfonylation in the presence of an external O‐nucleophile to deliver 1‐azabicyclo[3.2.0]heptenes in high yields.