Back Cover: Non‐Porous Iron(II)‐Based Sensor: Crystallographic Insights into a Cycle of Colorful Guest‐Induced Topotactic Transformations (Angew. Chem. Int. Ed. 48/2016). Issue 48 (21st November 2016)

• Record Type: Journal Article
• Authors: Rodríguez‐Jiménez, Santiago; Feltham, Humphrey L. C.; Brooker, Sally
• Is Part Of: Angewandte Chemie international edition. Volume 55:Issue 48(2016)
• Page Start: 15182
• Page End: 15182
• Publication Date: 2016-11-21
• Subjects: chemical sensor -- crystal engineering -- reversible guest exchange -- single-crystal-to-single-crystal transformation -- spin crossover; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201610433
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract : Three guests, three colors In their Communication onpage 15067 ff., S. Brooker et al. demonstrate reversible three‐way guest sensing by a diiron(II) complex, which results in interconversion of a dark red low‐spin form1, an orange high‐spin form2, and a yellow form3 . Remarkably, these guest exchanges are reversible single‐crystal to single‐crystal (SCSC) transformations, and1 →3 involves a polymerization→depolymerization. Cover art: Michael Crawford (Dunedin).