Bio-inspired enantioselective full transamination using readily available cyclodextrin12. Issue 7 (16th January 2017)

• Record Type: Journal Article
• Authors: Zhang, Shiqi; Li, Guangxun; Liu, Hongxin; Wang, Yingwei; Cao, Yuan; Zhao, Gang; Tang, Zhuo
• Is Part Of: RSC advances. Volume 7:Issue 7(2017)
• Page Start: 4203
• Page End: 4208
• Publication Date: 2017-01-16
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c6ra27525g
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : The mimics of vitamin B6 -dependent enzymes that catalyzed an enantioselective full transamination in the pure aqueous phase have been realized through the establishment of a new catalytical system with readily available β-cyclodextrin. Abstract : The mimics of vitamin B6 -dependent enzymes that catalyzed an enantioselective full transamination in the pure aqueous phase have been realized for the first time through the establishment of a new "pyridoxal 5′-phosphate (PLP) catalyzed non-covalent cyclodextrin (CD)-keto acid inclusion complexes" system, and various optically active amino acids have been obtained.