A perylene complex with a one-dimensional coordination polymer containing [Mn6O2(CHCl2COO)10(H2O)2] cluster units linked by 3, 10-perylenequinone bridges. (3rd January 2017)

• Record Type: Journal Article
• Authors: Kushch, Lyudmila A.; Kazakova, Anna V.; Mironova, Svetlana A.; Yagubskii, Eduard B.; Simonov, Sergey V.; Zorina, Leokadiya V.; Shibaeva, Rimma P.; Sadakov, Andrey V.; Mironov, Vladimir S.
• Is Part Of: New journal of chemistry. Volume 41:Number 2(2017)
• Page Start: 793
• Page End: 801
• Publication Date: 2017-01-03
• Subjects: Chemistry -- Periodicals; Chimie -- Périodiques; 540
• DOI: 10.1039/c6nj03097a
• Languages: English
• ISSNs: 1144-0546

Abstract

Abstract : The reactions of perylene with Mn12 oxodichloroacetate and oxobenzoate clusters were examined. Abstract : The crystals of a perylene complex with the polymeric cluster containing [Mn6 O2 (O2 CCHCl2 )10 (H2 O)2 ] units assembled by 3, 10-perylenequinone bridges, {[Mn6 O2 (O2 CCHCl2 )10 (H2 O)2 (C20 H10 O2 )]2 n ·(C20 H12 ) n } (I ), were obtained in the reaction of [Mn12 O12 (O2 CCHCl2 )16 (H2 O)4 ] with perylene. Unlike the Mn12 oxodichloroacetate cluster, the reaction of the Mn12 oxobenzoate cluster, [Mn12 O12 (O2 CPh)16 (H2 O)4 ], with perylene does not occur. However, it turned out that the crystals isolated from the reaction are a new Mn12 oxobenzoate cluster containing three molecules of coordinated H2 O and solvate molecules of hexane, [Mn12 O12 (O2 CC6 H5 )16 (H2 O)3 ]·2C6 H12 (II ). Crystal structures of complexesI andII as well as the magnetic properties of the former were studied.