Sub-micron pore size tailoring for efficient chiral discrimination. Issue 6 (3rd January 2017)

• Record Type: Journal Article
• Authors: Herling, Markus M.; Lacher, Ulrike; Rieß, Martin; Seibt, Sebastian; Schwedes, Mathias; Kalo, Hussein; Schobert, Rainer; Breu, Josef
• Is Part Of: Chemical communications. Volume 53:Issue 6(2017)
• Page Start: 1072
• Page End: 1075
• Publication Date: 2017-01-03
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c6cc09484h
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Microporous organically pillared layered silicates allow a pore size tuning in the sub-micron range, crucial for the efficient chiral discrimination of guest molecules. Abstract : Adsorption studies in microporous organically pillared layered silicates (MOPS) show that precise control of micropore size in the sub-Ångström range is crucial for chiral discrimination. The highly modular character of MOPS generally allows for an optimization of guest recognition without the need to explore different framework topologies.