A concise approach for central core of trigolutes: Total synthesis of trigolute B and 3-epi-trigolute B and analogues. Issue 7 (16th February 2017)
- Record Type:
- Journal Article
- Title:
- A concise approach for central core of trigolutes: Total synthesis of trigolute B and 3-epi-trigolute B and analogues. Issue 7 (16th February 2017)
- Main Title:
- A concise approach for central core of trigolutes: Total synthesis of trigolute B and 3-epi-trigolute B and analogues
- Authors:
- Reddy, B. Narendraprasad
Ramana, C.V. - Abstract:
- Abstract: A concise approach comprising a combination of the Pd- or Ir-catalyzed Tsuji-Trost allylation and olefin dihydroxylation/acid catalyzed lactonization has been developed to construct the central spirolactone core of trigolutes with the requisite functional groups. A large number of analogues of trigolute B have been synthesized. Furthermore, the synthesis of both (±)-trigolute B and (±)-3-epi-trigolute B has been accomplished in 4–5 steps from easily accessible building blocks. Graphical abstract:
- Is Part Of:
- Tetrahedron. Volume 73:Issue 7(2017)
- Journal:
- Tetrahedron
- Issue:
- Volume 73:Issue 7(2017)
- Issue Display:
- Volume 73, Issue 7 (2017)
- Year:
- 2017
- Volume:
- 73
- Issue:
- 7
- Issue Sort Value:
- 2017-0073-0007-0000
- Page Start:
- 888
- Page End:
- 899
- Publication Date:
- 2017-02-16
- Subjects:
- Trigolute B -- Tsuji-Trost allyation -- 3-epi-trigolute B -- Iridium -- Palladium -- Dihydroxylation/ lactonization
Chemistry, Organic -- Periodicals
547.005 - Journal URLs:
- http://www.elsevier.com/journals ↗
- DOI:
- 10.1016/j.tet.2016.12.074 ↗
- Languages:
- English
- ISSNs:
- 0040-4020
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8796.850000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 633.xml