High performance polymer solar cells with electron extraction and light-trapping dual functional cathode interfacial layer. (January 2017)

• Record Type: Journal Article
• Authors: Li, Cong; Zhu, Honglu; Wang, Yaping; Liu, Hao; Hu, Siqian; Wang, Fuzhi; Zhang, Bing; Dai, Songyuan; Tan, Zhan'ao
• Is Part Of: Nano energy. Volume 31(2017:Jan.)
• Page Start: 201
• Page End: 209
• Publication Date: 2017-01
• Subjects: Polymer solar cells -- Tantalum (V) methoxide (Ta-OMe) -- Electron extraction -- Light trapping -- Cathode interfacial layer; Nanoscience -- Periodicals; Nanotechnology -- Periodicals; Nanostructured materials -- Periodicals; Power resources -- Technological innovations -- Periodicals; Nanoscience; Nanostructured materials; Nanotechnology; Power resources -- Technological innovations; Periodicals; 621.042
• DOI: 10.1016/j.nanoen.2016.11.032
• Languages: English
• ISSNs: 2211-2855

Abstract

Abstract: For polymer solar cells (PSCs), the interfaces between the back and front contacts with the photoactive layer play a crucial role for charge extraction. Herein, we demonstrate high performance PSCs with dual functional tantalum methoxide (Ta-OMe) cathode interfacial layer, which can reduce the interface energy barrier and form a light trapping structure with reflective metal electrode. The energy level of Ta-OMe is investigated by ultraviolet photoelectron spectroscopy (UPS). The composition of the Ta-OMe film is confirmed by X-ray photoelectron spectroscopy (XPS). The surface morphologies of the photoactive layer with and without Ta-OMe layer are measured by scanning electron microscopy (SEM) and tapping mode atomic force microscopy (AFM). Three polymer donors with different band gaps and two classical fullerene acceptors were selected as photoactive materials for fabrication PSCs. The PSCs with Ta-OMe interfacial layer exhibit superior performance in comparison with devices which Al and Ca/Al based devices. The great enhancement in J sc is associated with additional absorption (ΔαAbs ) and the additional EQE (ΔαEQE ). The four parameters of V oc, J sc, FF, and PCE for device with Ta-OMe reach 0.80 V, 18.55 mA/cm 2, 70%, and 10.18%, respectively, among the best values reported for PTB7-Th:PC70 BM based PSCs. Graphical abstract: Highlights: High performance polymer solar cells modified with solution-processed tantalum methoxide (Ta-OMe) cathode buffer layer. Ta-OMe cathode interfacial layer bares electron extraction and light-trapping dual functions. With Ta-OMe interfacial layer, the power conversion efficiency of the PSC based on PTB7-Th:PC71 BM reaches10.18%.