Substituent effects in the asymmetric Diels-Alder cycloaddition of 3, 4, 5-triaryl-1-(+)-neomenthyl-1, 2-diphospholes' with maleic acid derivatives. (1st December 2016)

• Record Type: Journal Article
• Authors: Oshchepkova, Elena S.; Zagidullin, Almaz A.; Miluykov, Vasili A.; Sinyashin, Oleg G.
• Is Part Of: Phosphorus, sulfur, and silicon and the related elements. Volume 191:Number 11/12(2016)
• Page Start: 1530
• Page End: 1532
• Publication Date: 2016-12-01
• Subjects: Asymmetric synthesis -- cycloaddition -- phosphorus heterocycles -- chiral phosphanes -- P-chiral; Sulfur compounds -- Periodicals; Organosulfur compounds -- Periodicals; Phosphorus compounds -- Periodicals; Organophosphorus compounds -- Periodicals; Silicon compounds -- Periodicals; Organosilicon compounds -- Periodicals; 546
• DOI: 10.1080/10426507.2016.1212350
• Languages: English
• ISSNs: 1042-6507

Abstract

GRAPHICAL ABSTRACT: ABSTRACT: Asymmetric phospha-Diels-Alder reactions involving new 3, 4, 5-triaryl-1-(+)-neomenthyl-1, 2-diphosphole bearing a chiral auxiliary with maleic acid derivatives with diastereoselectivities up to 91% are described.