10-(Aryl)phenoxarsines as ligands for design of polynuclear Cu(I) complexes. (1st December 2016)

• Record Type: Journal Article
• Authors: Sattarova, Liliya S.; Wittmann, Tatiana I.; Galimova, Milyausha F.; Musin, Rustem R.; Musina, Elvira I.; Karasik, Andrey A.; Sinyashin, Oleg G.
• Is Part Of: Phosphorus, sulfur, and silicon and the related elements. Volume 191:Number 11/12(2016)
• Page Start: 1587
• Page End: 1588
• Publication Date: 2016-12-01
• Subjects: 10-(Aryl)phenoxarsines -- copper complexes -- coordination polymer; Sulfur compounds -- Periodicals; Organosulfur compounds -- Periodicals; Phosphorus compounds -- Periodicals; Organophosphorus compounds -- Periodicals; Silicon compounds -- Periodicals; Organosilicon compounds -- Periodicals; 546
• DOI: 10.1080/10426507.2016.1216422
• Languages: English
• ISSNs: 1042-6507

Abstract

GRAPHICAL ABSTRACT: ABSTRACT: Heteroleptic or homoleptic dinuclear complexes with stoichiometry Cu2 I2 L2 Py2 and Cu2 I2 L4 are obtained by reaction of 10-(aryl)phenoxarsine ligands with copper iodide in pyridine in the equimolar ratio and in a 1 : 2 stoichiometry using non-coordinating solvent respectively. Unexpectedly only 1D polymeric complex [CuIL2]n is formed by the reaction of 10-(ethoxyphenyl)phenoxarsine with CuI in the molar ratio 1 : 2.