Ru-catalyzed ortho-oxidative alkenylation of 2-arylbenzo[d]thiazoles in aqueous solution of anionic surfactant sodium dodecylbenzenesulfonate (SDBS). Issue 5 (2nd February 2017)

• Record Type: Journal Article
• Authors: Ping, Yuanyuan; Chen, Zhaobin; Ding, Qiuping; Zheng, Qiang; Lin, Yuqing; Peng, Yiyuan
• Is Part Of: Tetrahedron. Volume 73:Issue 5(2017)
• Page Start: 594
• Page End: 603
• Publication Date: 2017-02-02
• Subjects: Alkenylation -- C–H functionalization -- 2-arylbenzo[d]thiazoles -- 2-arylthiazoles -- Aqueous; Chemistry, Organic -- Periodicals; 547.005
• DOI: 10.1016/j.tet.2016.12.050
• Languages: English
• ISSNs: 0040-4020

Abstract

Abstract: A mild and efficient Ru-catalyzed ortho -oxidative alkenylation of 2-arylbenzo[ d ]thiazoles through twofold C-H bond functionalization in aqueous solution of anionic surfactant sodium dodecylbenzenesulfonate (SDBS) has been developed using activated olefins as coupling partner. The protocol could be carried out smoothly on a gram scale, recyclable, and applicable to 2-arylthiazoles. Graphical abstract: