Catalytic [2+2+1] Synthesis of Fused Thiophenes Using Thiocarbonyls as Sulfur Donors. (11th November 2016)
- Record Type:
- Journal Article
- Title:
- Catalytic [2+2+1] Synthesis of Fused Thiophenes Using Thiocarbonyls as Sulfur Donors. (11th November 2016)
- Main Title:
- Catalytic [2+2+1] Synthesis of Fused Thiophenes Using Thiocarbonyls as Sulfur Donors
- Authors:
- Matsui, Kazuma
Shibuya, Masatoshi
Yamamoto, Yoshihiko - Abstract:
- Abstract: The use of N ‐( p ‐chlorophenyl)methylbenzoxazole‐2‐thione as a sulfur‐atom donor enables the catalytic [2+2+1] cycloaddition of diynes in wet DMF at 80 °C when open to air, thus affording diverse fused thiophenes with good yields and wide functional‐group compatibility. A plausible mechanism, involving a cationic ruthenacycle intermediate, was also proposed on the basis of several control experiments.
- Is Part Of:
- Angewandte Chemie. Volume 128:Number 49(2016)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 128:Number 49(2016)
- Issue Display:
- Volume 128, Issue 49 (2016)
- Year:
- 2016
- Volume:
- 128
- Issue:
- 49
- Issue Sort Value:
- 2016-0128-0049-0000
- Page Start:
- 15623
- Page End:
- 15626
- Publication Date:
- 2016-11-11
- Subjects:
- Alkine -- Cycloadditionen -- Reaktionsmechanismen -- Ruthenium -- Schwefelheterocyclen
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201609545 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 1153.xml