A Germylene Stabilized by Homoconjugation. (17th November 2016)
- Record Type:
- Journal Article
- Title:
- A Germylene Stabilized by Homoconjugation. (17th November 2016)
- Main Title:
- A Germylene Stabilized by Homoconjugation
- Authors:
- Dong, Zhaowen
Reinhold, Crispin R. W.
Schmidtmann, Marc
Müller, Thomas - Abstract:
- Abstract: The synthesis of a bicyclic germylene from the reaction of a germole dianion with hafnocene dichloride is reported. This germylene is stabilized by a homoconjugative interaction of the dicoordinated germanium atom with a remote C=C double bond. First reactivity studies revealed its nucleophilic character and resulted in the synthesis of bimetallic hafnium/iron and hafnium/tungsten complexes with a germylene group linker.
- Is Part Of:
- Angewandte Chemie. Volume 128:Number 51(2016)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 128:Number 51(2016)
- Issue Display:
- Volume 128, Issue 51 (2016)
- Year:
- 2016
- Volume:
- 128
- Issue:
- 51
- Issue Sort Value:
- 2016-0128-0051-0000
- Page Start:
- 16131
- Page End:
- 16136
- Publication Date:
- 2016-11-17
- Subjects:
- Carben-Analoga -- Germanium -- Homokonjugation -- Hyperkonjugation -- Röntgenbeugung
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201609576 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 533.xml