Alkyl-and arylsulfanyl-substituted unsaturated carbonyl compounds. (2nd January 2017)
- Record Type:
- Journal Article
- Title:
- Alkyl-and arylsulfanyl-substituted unsaturated carbonyl compounds. (2nd January 2017)
- Main Title:
- Alkyl-and arylsulfanyl-substituted unsaturated carbonyl compounds
- Authors:
- Kondrashov, Evgeniy V.
Romanov, Alexey R.
Ushakov, Igor A.
Rulev, Alexander Yu. - Abstract:
- ABSTRACT: A method for the synthesis of captodative sulfanyl enals, enones and enoates via nucleophilic vinylic substitution of corresponding halogen-bearing derivatives has been developed. The one-pot treatment of the haloenoates, haloenones or haloenals with thiols in the presence of organic base leads either to vicinal dithiosubstituted carbonyl-bearing compound or captodative systems with good to excellent yield. The major reaction direction strongly depends on the type of base used. GRAPHICAL ABSTRACT:
- Is Part Of:
- Journal of sulfur chemistry. Volume 38:Number 1(2017)
- Journal:
- Journal of sulfur chemistry
- Issue:
- Volume 38:Number 1(2017)
- Issue Display:
- Volume 38, Issue 1 (2017)
- Year:
- 2017
- Volume:
- 38
- Issue:
- 1
- Issue Sort Value:
- 2017-0038-0001-0000
- Page Start:
- 18
- Page End:
- 33
- Publication Date:
- 2017-01-02
- Subjects:
- Thiols -- nucleophilic vinylic substitution -- thia-Michael -- unsaturated sulfides -- halogenophilic reaction
Sulfur -- Periodicals
Chemistry, Inorganic -- Periodicals
546.72305 - Journal URLs:
- http://www.tandfonline.com/loi/gsrp20 ↗
http://www.tandfonline.com/ ↗ - DOI:
- 10.1080/17415993.2016.1215448 ↗
- Languages:
- English
- ISSNs:
- 1741-5993
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 5067.107500
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 2746.xml