A Critical Review of Discrete Soil Sample Data Reliability: Part 2—Implications. Issue 1 (2nd January 2017)

• Record Type: Journal Article
• Authors: Brewer, Roger; Peard, John; Heskett, Marvin
• Is Part Of: Soil & sediment contamination. Volume 26:Issue 1(2017)
• Page Start: 23
• Page End: 44
• Publication Date: 2017-01-02
• Subjects: Soil sample -- sampling theory -- Multi Increment sample -- incremental sampling methodology -- environmental site investigation; Soil pollution -- Periodicals; Soil protection -- Periodicals; 628.5505
• DOI: 10.1080/15320383.2017.1244172
• Languages: English
• ISSNs: 1532-0383

Abstract

ABSTRACT: Part 2 of this study investigates the implications of random, small-scale contaminant concentration variability in soil for reliance on discrete soil sample data to guide environmental investigations. Random variability around an individual point limits direct comparison of discrete sample data to risk-based screening levels. "False negatives" can lead to premature termination of an investigation or remedial action. Small-scale distributional heterogeneity of contaminants in soil is expressed as artificial, seemingly isolated "hot spots" and "cold spots" in isoconcentration maps. Surgical removal of hot spots can lead to erroneous conclusions regarding the magnitude of remaining contamination. The field precision of an individual discrete sample data set for estimation of means for a contaminant in a risk assessment is not directly testable. Omission of "outlier" data in order to force data to fit a geostatistical model distorts estimates of mean concentrations and introduces error into a risk assessment. The potential for such errors was pointed out in early USEPA guidance but largely ignored or misunderstood. Decision Unit and Multi Increment sample investigation methods, long known to the agricultural and mining industries, were specifically developed to overcome these inherent shortcomings of discrete sampling methods and provide more reliable and defensible data for environmental investigations.