Characterization of hydrogen storage properties of Mg-Fe-CNT composites prepared by ball milling, hot-extrusion and severe plastic deformation methods. (28th December 2016)

• Record Type: Journal Article
• Authors: de Lima Andreani, Gisele Ferreira; Triques, Maria Regina Martins; Kiminami, Claudio Shyinti; Botta, Walter Jose; Roche, Virginie; Jorge, Alberto Moreira
• Is Part Of: International journal of hydrogen energy. Volume 41:Number 48(2016)
• Page Start: 23092
• Page End: 23098
• Publication Date: 2016-12-28
• Subjects: Complex hydrides -- Mg2FeH6 -- Nanotubes -- Composites -- Hydrogen sorption properties; Hydrogen as fuel -- Periodicals; Hydrogène (Combustible) -- Périodiques; Hydrogen as fuel; Periodicals; 665.81
• DOI: 10.1016/j.ijhydene.2016.10.095
• Languages: English
• ISSNs: 0360-3199

Abstract

Abstract: A systematic investigation was performed on the hydrogen storage properties of mechanically prepared 2MgFe/carbon nanotube (CNT) composites. The powders were transformed into bulk form by three processing routes (hot-extrusion, cold-rolling and extrusion followed by cold-rolling). The samples were kept in air to test their resistance to oxidation. Hydrogen absorption capacity and hydriding kinetics of the composites were dependent on the quantity of added CNTs. A 5 wt% addition of CNTs is optimum to facilitate the hydrogen absorption and desorption. Single cold-rolling (CR) was found to be the best route. Compared with powder composites, samples prepared by CR presented improved kinetics, the same hydrogen capacity and a decrease in the incubation time for activation. The cold-rolled composite 2MgFe/5 wt% CNTs achieved 73% of the theoretical capacity of Mg2 FeH6, and desorbs almost the same quantity. Moreover, these absorption and desorption processes occur faster than in the powders. Highlights: 2Mg-Fe/carbon nanotubes (CNTs) composites were produced by several routes. Ball milling, hot-extrusion, cold-rolling and combined processing routes were used. Ball milling plus cold-rolling proved to be the best route. CNTs were not destroyed after mechanical processing, bulk Mg2 FeH6 was produced. The greater the amounts of CNT (max = 5 wt%), the better the H-absorption properties.