Ammonothermal Synthesis and Characterization of Cs2[Zn(NH2)4]. Issue 21 (7th October 2016)
- Record Type:
- Journal Article
- Title:
- Ammonothermal Synthesis and Characterization of Cs2[Zn(NH2)4]. Issue 21 (7th October 2016)
- Main Title:
- Ammonothermal Synthesis and Characterization of Cs2[Zn(NH2)4]
- Authors:
- Richter, Theresia M. M.
Alt, Nicolas S. A.
Schlücker, Eberhard
Niewa, Rainer - Abstract:
- Abstract : Cs2 [Zn(NH2 )4 ] was synthesized under ammonothermal conditions (sc‐NH3, 523 K, 155 MPa) from CsNH2 and Zn. Growth of cm‐sized crystals succeeded upon application of a temperature gradient. The crystal structure is based on the motif of a hexagonal closed packing of [Zn(NH2 )4 ] 2– ions with occurrence of no significant hydrogen bridges according to distances and vibrational spectroscopy. Cs + ions are located within octahedral and tetrahedral holes of the packing. Abstract :
- Is Part Of:
- Zeitschrift für anorganische und allgemeine Chemie. Volume 642:Issue 21(2016)
- Journal:
- Zeitschrift für anorganische und allgemeine Chemie
- Issue:
- Volume 642:Issue 21(2016)
- Issue Display:
- Volume 642, Issue 21 (2016)
- Year:
- 2016
- Volume:
- 642
- Issue:
- 21
- Issue Sort Value:
- 2016-0642-0021-0000
- Page Start:
- 1207
- Page End:
- 1211
- Publication Date:
- 2016-10-07
- Subjects:
- Kewords: Ammonothermal synthesis; Amides; Cesium; Zincates
Chemistry, Inorganic -- Periodicals
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1521-3749 ↗
http://onlinelibrary.wiley.com/ ↗ - DOI:
- 10.1002/zaac.201600287 ↗
- Languages:
- English
- ISSNs:
- 0044-2313
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 9452.000000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 2843.xml