The effects of free edge interaction-induced knotting on the buckling of monolayer graphene. (1st December 2016)

• Record Type: Journal Article
• Authors: Zhang, Hao-Yu; Jiang, Jin-Wu; Chang, Tienchong; Guo, Xingming; Park, Harold S.
• Is Part Of: International journal of solids and structures. Volume 100/101(2016)
• Page Start: 446
• Page End: 455
• Publication Date: 2016-12-01
• Subjects: Buckling -- Edge effect -- Knotting effect -- Graphene; Mechanics, Applied -- Periodicals; Structural analysis (Engineering) -- Periodicals; Elastic solids -- Periodicals; Mécanique appliquée -- Périodiques; Constructions, Théorie des -- Périodiques; Solides élastiques -- Périodiques; Elastic solids; Mechanics, Applied; Structural analysis (Engineering); Periodicals; 624.18
• DOI: 10.1016/j.ijsolstr.2016.09.017
• Languages: English
• ISSNs: 0020-7683

Abstract

Abstract: Edge effects play an important role for many properties of graphene. While most works have focused on the effects from isolated free edges, we present a novel knotting phenomenon induced by the interactions between a pair of free edges in graphene, and investigate its effect on the buckling of monolayer graphene. Upon compression, the buckling of graphene starts gradually in the form of two buckling waves from the warped edges. The collision of these two buckling waves results in the creation of a knot structure in graphene. The knot structure enables the buckled graphene to exhibit two unique post-buckling characteristics. First, it induces a five-fold increase in graphene's mechanical stiffness during the buckling process. Second, the knotted structure enables graphene to exhibit a mechanically stable post-buckling regime over a large (3%) compressive strain regime, which is significantly larger than the critical buckling strain of about 0.5%. The combination of these two effects enables graphene to exhibit an unexpected post-buckling stability that has previously not been reported. We predict that numerical simulations or experiments should observe two distinct stress strain relations for the buckling of identical graphene samples, due to the characteristic randomness in the formation process of the knot structure.