Effect of surfactants on the morphologies of TiO2 particles with high-performance scattering layer in dye-sensitized solar cells. (15th January 2017)

• Record Type: Journal Article
• Authors: Lekphet, Woranan; Ke, Tsai-Chyuan; Su, Chaochin; Sireesha, Pedaballi; Kathirvel, Sasipriya; Lin, Ya-Fen; Chen, Bo-Ren; Li, Wen-Ren
• Is Part Of: Solar energy. Volume 142(2017)
• Page Start: 1
• Page End: 12
• Publication Date: 2017-01-15
• Subjects: Dye-sensitized solar cells -- Hydrothermal method -- Surfactants -- Star-shape -- Rod-shape -- Flower-shape -- Scree-shape TiO2; Solar energy -- Periodicals; Solar engines -- Periodicals; 621.47
• DOI: 10.1016/j.solener.2016.12.017
• Languages: English
• ISSNs: 0038-092X

Abstract

Graphical abstract: Highlights: A various TiO2 morphologies were prepared by TANHs surfactant v ia controlled hydrothermal process. Star-, flower-, short rod-, scree-shaped TiO2 particles were used as scattering layers photoanodes in DSSCs. TBAH surfactant based scree-shaped TiO2 nanoparticles achieved the highest power conversion efficiency as 9.86%. DSSCs based on the weight ratios TB-TiO2 / a -TiO2 of (2:3) composites had the maximum conversion efficiency of 10.53%. Abstract: A series of TiO2 powders with various morphologies were synthesized using surfactant-assisted hydrothermal method by hydrolyzing the titanium tetra-isopropoxide (TTIP) precursor. Four types of tetraalkylammonium hydroxide (TANH) surfactants such as tetramethylammonium hydroxide (TMAH), tetraethylammonium hydroxide (TEAH), tetrapropylammomium hydroxide (TPAH), and tetrabutylammonium hydroxide (TBAH) were used before hydrothermal crystallization. The results showed that the surfactants with different alkyl chain length of tetraalkylammonium cations (TAN + ) had a great influence on the morphology, particle size, and crystalline phase of TiO2 particles. Under the same experimental conditions, the surfactants of TMAH, TEAH, TPAH, and TBAH resulting in the star-, flower-, rod-, and scree-shaped TiO2 particles (TM-, TE-, TP-, and TB-TiO2 ), respectively. The particle sizes were decreased in the range from ∼3.6 μm to ∼220 nm while increasing the alkyl chain length of the surfactants. All the TiO2 powders showed an anatase phase besides the TiO2 prepared from TMAH surfactant. The photovoltaic investigations of these TiO2 samples as the scattering layer in DSSCs indicated that the TB-TiO2 based cell exhibited the excellent power conversion efficiency of 9.88%, which was also higher than that of a device which fabricated without a scattering layer (8.83%). Among these scattering layers, TB-TiO2 has the optimum particle size (∼220 nm) with the highest surface area leading to the largest dye adsorption value and an excellent efficiency. In order to further increase the dye adsorption of the photoanodes, the scattering layer was prepared by mixing the large (TB-TiO2 ) and small sized ( a -TiO2 ) particles as composites with different weight ratios, leading to the highest efficiency of 10.53% at TB-/ a -TiO2 (2:3).