TL studies of a sensitive CaNa2(SO4)2:Dy nanophoshor for gamma dosimetry. (January 2017)

• Record Type: Journal Article
• Authors: Bhadane, Mahesh S.; Dahiwale, S.S.; Sature, K.R.; Patil, B.J.; Bhoraskar, V.N.; Dhole, S.D.
• Is Part Of: Radiation measurements. Volume 96(2017:Jan.)
• Page Start: 1
• Page End: 7
• Publication Date: 2017-01
• Subjects: CaNa2(SO4)2:Dy -- 60Co-gamma source -- Dosimetry -- TL -- Sensitivity; Nuclear emulsions -- Periodicals; Particle tracks (Nuclear physics) -- Periodicals; Thermoluminescence -- Periodicals; Cosmic rays -- Periodicals; Radiation -- Measurement -- Periodicals; Radiometry -- Periodicals; Radiation Monitoring -- Periodicals; Émulsions nucléaires -- Périodiques; Particules (Physique nucléaire) -- Traces -- Périodiques; Thermoluminescence -- Périodiques; Rayonnement cosmique -- Périodiques; Radiométrie -- Périodiques; 539.77
• DOI: 10.1016/j.radmeas.2016.11.009
• Languages: English
• ISSNs: 1350-4487

Abstract

Abstract: A new Dy doped CaNa2 (SO4 )2 nanophosphor has been synthesized using simple co-precipitation method and claimed to have good Thermoluminescence (TL) dosimetric properties. Structural, morphological, optical, compound identification and thermal analysis of the nanophosphor was studied by X-ray diffraction (XRD), High-Resolution Transmission electron microscope i.e. (HRTEM), UV–Visible, FTIR and TGA-DSC techniques. XRD studies showed a monoclinic structure and size of the particle found to be around ∼45 nm. HRTEM confirms the nanosize of the particles of the same order and SEAD pattern shows fringes perfectly match with inter planner spacing distance "d" of XRD i.e. 2.74 Å. UV–Visible and FTIR analysis revealed the absorption wavelength 246 nm which corresponds to the band gap of around ∼5.03 eV and formation of the compounds of different bonds such as S-O, S=O, SO4 stretch, SS disulfide, respectively. The percentage of weight loss-gain, endothermic changes of the nanophosphor was measured using TGA-DSC analysis and corresponding weight loss of such a nanophosphor with increasing temperature was observed around 12.60%. The TL analysis shows that the CaNa2 (SO4 )2 :Dy has a typical single glow curve at 164 °C and gives excellent linear response curve over a wide range of gamma dose from 10 Gy to 10 kGy. Moreover, the reproducibility of the CaNa2 (SO4 )2 :Dy nanophosphor did not change after numerous cycles of exposures and readouts. Fading has been observed at around 9.55% for 30 days. Theoretical analysis of glow curves of samples irradiated by γ-rays was done by computerized glow curve deconvolution (CGCD) method to find out trapping parameters of various peaks. Finally, CaNa2 (SO4 )2 :Dy nanophosphor could be a potential candidate for applications in the field of accidental and reactor dosimetry. Highlights: A new nanophosphor of CaNa2 (SO4 )2 doped with Dy for TL studies is reported. Chemical Co-precipitation method has been used for the synthesis of nanophosphor. XRD, HRTEM, UV–Visible, FTIR and TGA-DSC Properties of nanophosphor have been studied. TL intensity showed linear dose response from 10 Gy to 10 kGy. Such a phosphor can be utilized for medical, accidental and reactor dosimetry.