Aromatic ring hydrogenation catalysed by nanoporous montmorillonite supported Ir(0)-nanoparticle composites under solvent free conditions. (1st February 2016)

• Record Type: Journal Article
• Authors: Das, Prabin; Sarmah, Podma Pollov; Borah, Bibek Jyoti; Saikia, Lakshi; Dutta, Dipak Kumar
• Is Part Of: New journal of chemistry. Volume 40:Number 3(2016:Mar.)
• Page Start: 2850
• Page End: 2855
• Publication Date: 2016-02-01
• Subjects: Chemistry -- Periodicals; Chimie -- Périodiques; 540
• DOI: 10.1039/c5nj03030g
• Languages: English
• ISSNs: 1144-0546

Abstract

Abstract : Ir nanoparticles supported on nanoporous montmorillonite clay showing efficient catalytic activity for hydrogenation of aromatic compounds. Abstract : Ir(0)-nanoparticles (Ir-NPs) were synthesized into the nanopores of modified montmorillonite clay by incipient wetness impregnation of IrCl3 followed by reduction with ethylene glycol. The activation of the montmorillonite clay was carried out by treatment with HCl under controlled conditions to increase the surface area by generating nanopores which act as host for the metal nanoparticles. The synthesized Ir-NP–montmorillonite composites were characterized by N2 -sorption, powder XRD, SEM, EDS, TEM, XPS, etc . The composites exhibit high surface area of 327 m 2 g −1 and the Ir-NPs with size around 4 nm are uniformly distributed on the support. The Ir-NPs show efficient catalytic activity in aromatic ring hydrogenation under solvent free conditions with maximum conversion up to 100% and Turn Over Frequency (TOF) up to 79 h −1 . The catalyst can be easily separated by simple filtration and remained active for several runs without significant loss of catalytic efficiency.