Alkyl-functionalization of 3, 5-bis(2-pyridyl)-1, 2, 4, 6-thiatriazine. (25th January 2016)

• Record Type: Journal Article
• Authors: Kleisath, Elizabeth; Yutronkie, Nathan J.; Korobkov, Ilia; Gabidullin, Bulat M.; Brusso, Jaclyn L.
• Is Part Of: New journal of chemistry. Volume 40:Number 5(2016:May)
• Page Start: 4472
• Page End: 4479
• Publication Date: 2016-01-25
• Subjects: Chemistry -- Periodicals; Chimie -- Périodiques; 540
• DOI: 10.1039/c5nj02611c
• Languages: English
• ISSNs: 1144-0546

Abstract

Abstract : S -Alkyl-1, 2, 4, 6-thiatriazines, which can be prepared via two pathways, are described. The regioselectivity and photophysical properties are rationalized through computational studies. Abstract : A versatile synthetic route to prepare alkyl functionalized 3, 5-bis-(2-pyridyl)-1, 2, 4, 6-thiatriazines is described that can proceed either via cationic or anionic pathways; confirmed through characterization of the isolable intermediates. Computational studies are presented, which support the regioselectivity of the alkylation reactions and photophysical properties of the S -alkylated derivatives.