Tuning and enhancement of the Mizoroki–Heck reaction using polarized Pd nanocomposite carbon aerogels. (3rd November 2016)
- Record Type:
- Journal Article
- Title:
- Tuning and enhancement of the Mizoroki–Heck reaction using polarized Pd nanocomposite carbon aerogels. (3rd November 2016)
- Main Title:
- Tuning and enhancement of the Mizoroki–Heck reaction using polarized Pd nanocomposite carbon aerogels
- Authors:
- Martín, Laura
Molins, Elies
Vallribera, Adelina - Abstract:
- Abstract : The application of a positive electric field on a Pd(0)–carbon aerogel nanocomposite catalyst enhances the reaction rate of a Mizoroki–Heck reaction. Abstract : The application of a positive electric field on a Pd(0)–carbon aerogel nanocomposite enhances the reaction rate of the Mizoroki–Heck reaction. By contrast, when a negative potential is employed the reaction is inhibited. On the other hand, chronoamperometry measurements have revealed the polarizing current intensity as an indirect measure of the reaction evolution. The cationic nature of the reaction intermediates was unambiguously confirmed and a polar mechanism has been finally proposed.
- Is Part Of:
- New journal of chemistry. Volume 40:Number 12(2016:Dec.)
- Journal:
- New journal of chemistry
- Issue:
- Volume 40:Number 12(2016:Dec.)
- Issue Display:
- Volume 40, Issue 12 (2016)
- Year:
- 2016
- Volume:
- 40
- Issue:
- 12
- Issue Sort Value:
- 2016-0040-0012-0000
- Page Start:
- 10208
- Page End:
- 10212
- Publication Date:
- 2016-11-03
- Subjects:
- Chemistry -- Periodicals
Chimie -- Périodiques
540 - Journal URLs:
- http://www.rsc.org/ ↗
http://www.rsc.org/is/journals/current/newjchem/njc.htm ↗ - DOI:
- 10.1039/c6nj02279k ↗
- Languages:
- English
- ISSNs:
- 1144-0546
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 6084.319900
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 176.xml