A chemodosimetric approach for the selective detection of Pb2+ ions using a cesium based perovskite. (17th October 2016)

• Record Type: Journal Article
• Authors: Aamir, Muhammad; Sher, Muhammad; Malik, Muhammad Azad; Akhtar, Javeed; Revaprasadu, Neerish
• Is Part Of: New journal of chemistry. Volume 40:Number 11(2016:Nov.)
• Page Start: 9719
• Page End: 9724
• Publication Date: 2016-10-17
• Subjects: Chemistry -- Periodicals; Chimie -- Périodiques; 540
• DOI: 10.1039/c6nj01783e
• Languages: English
• ISSNs: 1144-0546

Abstract

Abstract : We have synthesized a lead free inorganic perovskite as a fluorescence turn-on chemodosimeter for selective sensing of Pb 2+ ions. Abstract : We report the preparation of a lead free inorganic perovskite by a facile wet-chemical method using HCl as a solvent at room temperature. The cesium perovskite CsCuCl3 material was characterized by powdered X-ray diffraction (p-XRD), field emission scanning electron microscopy (FESEM), and energy dispersive X-ray (EDX) spectroscopy. Ultraviolet/Visible (UV-Vis) and steady state photoluminescence (PL) spectroscopy were also carried out on the material. CsCuCl3 showed promising optical properties with a band gap of 2.6 eV. The material was tested as a fluorescent sensor for the detection of metal ions and as a selective fluorescent chemodosimeter for Pb 2+ ions. The substitution of Cu 2+ ions by Pb 2+ in CsCuCl3 proves the success of the chemodosimetry approach for the detection of Pb 2+ ions.