Solution-processable bipolar S, S-dioxide-dibenzothiophene chromophores for single-layer organic light-emitting diodes. (22nd July 2016)

• Record Type: Journal Article
• Authors: Zhao, Sen; Xie, Yuan; Liang, Junfei; Guo, Ting; Ying, Lei; Wu, Hongbin; Yang, Wei; Peng, Junbiao; Cao, Yong
• Is Part Of: New journal of chemistry. Volume 40:Number 9(2016:Sep.)
• Page Start: 7741
• Page End: 7749
• Publication Date: 2016-07-22
• Subjects: Chemistry -- Periodicals; Chimie -- Périodiques; 540
• DOI: 10.1039/c6nj00843g
• Languages: English
• ISSNs: 1144-0546

Abstract

Abstract : Four novel solution processable small molecular chromophores that consist of regioisomeric S, S -dioxide-dibenzothiophene units are designed and synthesized. Abstract : A series of novel bipolar chromophores consisting of a 4-(9 H -carbazole-9-yl)aniline (TCz) moiety as the electron-donating unit and an isomeric meta - or para -linked S, S -dioxide-dibenzothiophene (SO) unit as the electron-withdrawing unit were designed and synthesized. These chromophores exhibited obvious intramolecular charge transfer effects as revealed by photoluminescence spectra. All chromophores exhibited good thermal stabilities. The UV-vis absorption, photoluminescence, and electrochemical properties of these chromophores can be dramatically affected by the isomeric linkage of the SO unit, and the alkylfluorene unit that was incorporated between the SO unit and N-atoms in the 4-(9 H -carbazole-9-yl)aniline moiety. The resulting chromophores exhibited moderate electroluminescence properties. The best device performance is attained based on compoundM-3, which exhibited a peak luminous efficiency of 5.6 cd A −1 and a luminescence of 16 390 cd m −2 with a turn on voltage of 2.4 V and CIE coordinates of (0.31, 0.58). These results indicated that bipolar architectures can be a promising molecular design strategy for the synthesis of organic semiconductors with efficient light emission.