Environmentally weathered residues source diagnostic by high-molecular-weight polycyclic aromatic sulphur heterocycles. Issue 15 (7th December 2016)

• Record Type: Journal Article
• Authors: Hegazi, Abdelrahman H.; Fathalla, Eiman M.; Andersson, Jan T.
• Is Part Of: International journal of environmental analytical chemistry. Volume 96:Issue 15(2016)
• Page Start: 1469
• Page End: 1479
• Publication Date: 2016-12-07
• Subjects: Pollution monitoring -- high-molecular weight sulphur aromatics -- weathered residues -- fingerprinting -- Fourier transform ion cyclotron resonance mass spectrometry; Ecology -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental chemistry -- Periodicals; Pollution -- Periodicals; 577.14
• DOI: 10.1080/03067319.2016.1271418
• Languages: English
• ISSNs: 0306-7319

Abstract

ABSTRACT: High-molecular-weight polycyclic aromatic sulphur heterocycles (HMPASH) were applied in a forensic chemical analysis to identify the source(s) of environmentally weathered residues polluting the beaches of the Mediterranean city of Alexandria, Egypt, and to assess their weathering trends. The HMPASH were investigated by Fourier transform ion cyclotron resonance mass spectrometry in residues and an Egyptian crude as a possible source oil. The dibenzothiophenes/naphthenodibenzothiophenes (DBE 9/DBE 10) parameter indicated that two studied residues were likely to have originated from Egyptian crude oils, whereas the third residue could have had a foreign source. The residues displayed different stages of weathering. HMPASH having double bond equivalent (DBE) 1–5 were more influenced by weathering processes than those having DBE 6–17, probably because they are aliphatic sulphides and not aromatic compounds.