Facile, ethylene glycol-promoted microwave-assisted solvothermal synthesis of high-performance LiCoPO4 as a high-voltage cathode material for lithium-ion batteries. Issue 86 (1st September 2016)

• Record Type: Journal Article
• Authors: Ludwig, Jennifer; Marino, Cyril; Haering, Dominik; Stinner, Christoph; Nordlund, Dennis; Doeff, Marca M.; Gasteiger, Hubert A.; Nilges, Tom
• Is Part Of: RSC advances. Volume 6:Issue 86(2016)
• Page Start: 82984
• Page End: 82994
• Publication Date: 2016-09-01
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c6ra19767a
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : A simple and rapid microwave-assisted solvothermal synthesis delivers hexagonal platelets of LiCoPO4 with tuned crystal orientations and leading-edge electrochemical properties. Abstract : Olivine-type LiCoPO4 is considered a promising high-voltage cathode material for next-generation lithium-ion batteries. However, preparing high-performance LiCoPO4 by a simple approach has been challenging. Herein, we present a facile and rapid (30 min) one-step microwave-assisted solvothermal synthesis route using a 1 : 1 (v/v) water/ethylene glycol (EG) binary solvent mixture and a temperature of 250 °C. The technique delivers high-performance LiCoPO4 nanoparticles without additional post-annealing or carbon coating steps. The as-prepared powder consists of single crystalline LiCoPO4 and features a hexagonal platelet-like morphology with dimensions of 700–800 nm × 400–600 nm × 100–220 nm. Selected area electron diffraction (SAED) experiments reveal that the platelets show the smallest dimension along [010], which is the direction of the lithium diffusion pathways in the olivine crystal structure. Furthermore, the results indicate that the EG co-solvent plays an important role in tailoring the particle size, morphology, and crystal orientation of the material. Co L-edge soft X-ray absorption spectroscopy (XAS) of LiCoPO4 are presented for the first time and confirm that the material only consists of Co 2+ . Benefiting from the unique morphology, which facilitates Li-ion conduction, electrochemical measurements deliver an initial discharge capacity of 137 mA h g −1 at 0.1 C, a remarkably stable capacity retention of 68% after 100 cycles at 0.5 C, and a specific energy density of 658 W h kg −1 based on its capacity and voltage, which is the best performance of LiCoPO4 obtained from microwave-assisted solvothermal synthesis to date.