Biomolecule-assisted solvothermal synthesis of Cu2SnS3 flowers/RGO nanocomposites and their visible-light-driven photocatalytic activities. Issue 78 (4th August 2016)

• Record Type: Journal Article
• Authors: Vadivel, S.; Maruthamani, D.; Paul, Bappi; Dhar, Siddhartha Sankar; Habibi-Yangjeh, A.; Balachandran, S.; Saravanakumar, B.; Selvakumar, A.; Selvam, K.
• Is Part Of: RSC advances. Volume 6:Issue 78(2016)
• Page Start: 74177
• Page End: 74185
• Publication Date: 2016-08-04
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c6ra12068g
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : Elimination of organic pollutants from wastewaters under visible-light irradiation is a venerable challenge in the fields of environmental and material science. Abstract : Elimination of organic pollutants from wastewaters under visible-light irradiation is a venerable challenge in the fields of environmental and material science. In this work, we present a facile eco-friendly method to fabricate novel Cu2 SnS3 flowers/RGO (Cu2 SnS3 /RGO) nanocomposites via a solvothermal method usingl -cysteine as a sulphur source and linker. The crystal structure, morphology, purity, spectroscopic, and charge carrier separation properties of the synthesized samples were studied by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), field emission-scanning electron microscopy (FE-SEM), high resolution transmission electron microscopy (HR-TEM), and X-ray energy-dispersive spectroscopy (EDS), Raman spectroscopy, UV-vis diffuse reflectance spectroscopy (UV-vis DRS) and electrochemical impedance spectroscopy (EIS). The photocatalytic performance of the Cu2 SnS3 /RGO nanocomposites was evaluated by photocatalytic decolorization of eosin under visible-light irradiation. Results showed that the Cu2 SnS3 /RGO (3%) nanocomposite exhibits enhanced photocatalytic activity compared with the pure Cu2 SnS3 . The improved photocatalytic activity of the nanocomposite was mainly attributed to the formation of well-defined interface between Cu2 SnS3 and graphene sheets, which greatly enhance the charge carrier separation efficiency in the Cu2 SnS3 semiconductor.