Palladium‐Catalyzed Direct Cross‐Coupling of Carboranyllithium with (Hetero)Aryl Halides. Issue 49 (26th October 2016)

• Record Type: Journal Article
• Authors: Lu, Ju‐You; Wan, Hong; Zhang, Jianwei; Wang, Zhixuan; Li, Yang; Du, Yongmei; Li, Chunying; Liu, Zhao‐Tie; Liu, Zhong‐Wen; Lu, Jian
• Is Part Of: Chemistry. Volume 22:Issue 49(2016)
• Page Start: 17542
• Page End: 17546
• Publication Date: 2016-10-26
• Subjects: C(cage)−C(sp2) formation -- carboranyllithium -- cross-coupling -- direct C-arylation -- palladium; Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201603967
• Languages: English
• ISSNs: 0947-6539

Abstract

Abstract: A palladium‐catalyzed direct C‐arylation reaction of readily available cage carboranyllithium reagents with aryl halides has been developed for the first time. This method is applicable to a wide range of aryl halide substrates including aryl iodides, aryl bromides, and heteroaromatic halides. Abstract : Palladium‐catalyzed direct C‐arylation of readily available cage carboranyllithium reagents with aryl halides has been developed for the first time. This method is applicable to a wide range of aryl halide substrates including aryl iodides, aryl bromides, and heteroaromatic halides.