Compositionally Graded Cathode Material with Long‐Term Cycling Stability for Electric Vehicles Application. Issue 22 (22nd August 2016)

• Record Type: Journal Article
• Authors: Kim, Un‐Hyuck; Lee, Eung‐Ju; Yoon, Chong S.; Myung, Seung‐Taek; Sun, Yang‐Kook
• Is Part Of: Advanced energy materials. Volume 6:Issue 22(2016)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2016-08-22
• Subjects: Al‐substitution -- full concentration gradient -- layered NCM cathode -- lithium‐ion batteries -- long‐term cycling; Energy harvesting -- Materials -- Periodicals; Energy conversion -- Materials -- Periodicals; Energy storage -- Materials -- Periodicals; Photovoltaics -- Periodicals; Fuel cells -- Periodicals; Thermoelectric materials -- Periodicals; 621.31
• DOI: 10.1002/aenm.201601417
• Languages: English
• ISSNs: 1614-6832

Abstract

Abstract : Al is introduced into a compositionally graded cathode with average composition of Li[Ni0.61 Co0.12 Mn0.27 ]O2 (FCG61) whose Ni and Mn concentrations are designed to vary continuously within the cathode particle. The Al‐substituted full concentration gradient (Al‐FCG61) cathode is tested for 3000 cycles in a full‐cell, mainly to gauge its viability for daily charge/discharge cycles during the service life of electric vehicles (≈10 years). The Al‐substitution enables the Al‐FCG61 cathode to maintain 84% of its initial capacity even after 3000 cycles. It is demonstrated that the Al‐substitution strengthens the grain boundaries, substantiated by the mechanical strength data, thereby delaying the nucleation of microcracks at the phase boundaries which is shown to be the main reason for the cathode failure during long‐term cycling. It also shows that the Al‐substitution decreases the cation mixing and suppresses the deleterious formation of the secondary phase that likely initiates the microcracks. Unlike an NCA cathode, whose depth of discharge (DOD) must be limited to 60% for long‐term cycling, the proposed Al‐FCG61 cathode is cycled at 100% DOD for 3000 cycles to fully utilize its available capacity for maximum energy density and subsequent reduction in cost of the battery. Abstract : Al substituted compositionally graded NCM cathode (Al‐FCG61) shows its improved cycle life because Al‐substitution in NCM FCG61 cathode strengthens the grain boundaries, and thereby delays the nucleation of microcracks. The Al‐FCG61 cathodes are cycled at 100% depth of discharge for 3000 cycles showing capacity retention of 84% to fully use their available capacity and subsequent reduction of battery cost.