Effect of melt composition on crustal carbonate assimilation: Implications for the transition from calcite consumption to skarnification and associated CO2 degassing. (13th October 2016)

• Record Type: Journal Article
• Authors: Carter, Laura B.; Dasgupta, Rajdeep
• Is Part Of: Geochemistry, geophysics, geosystems. Volume 17:Number 10(2016:Oct.)
• Page Start: 3893
• Page End: 3916
• Publication Date: 2016-10-13
• Subjects: experimental petrology -- carbonate assimilation -- volcanic CO2 -- skarns; Geochemistry -- Periodicals; Geophysics -- Periodicals; Earth sciences -- Periodicals; 550.5
• DOI: 10.1002/2016GC006444
• Languages: English
• ISSNs: 1525-2027

Abstract

Abstract: Skarns are residue of relatively low‐temperature magma‐induced decarbonation in the crust largely associated with silicic plutons. Mafic magmatic intrusions are also capable of releasing excess CO2 due to carbonate assimilation. However, the effect of mafic to silicic melt evolution on the decarbonation processes, in addition to temperature controls on carbonate‐intrusive magmatic systems, particularly at continental arcs, remains unclear. In this study, experiments performed in a piston cylinder apparatus at midcrustal depth (0.5 GPa) at supersolidus temperatures (900–1200°C) document calcite interaction with andesite and dacite melts at equilibrium under closed‐system conditions at calcite saturation in a 1:1 melt‐calcite ratio by weight. With increasing silica content in the starting melt, at similar melt fractions and identical pressure, assimilation decreases drastically (≤65% andesite‐calcite to ≤18% dacite‐calcite). In conjunction, the CaO/SiO2 ratio in melts resulting from calcite assimilation in andesitic starting material is >1, but ≤0.3 in those formed from dacite‐calcite interaction. With increasing silica‐content in the starting melt skarn mineralogy, particularly wollastonite, increases in modal abundance while diopsidic clinopyroxene decreases slightly. More CO2 is released with andesite‐calcite reaction (≤2.9 × 10 11 g/y) than with more skarn‐like dacite‐calcite interaction (≤8.1 × 10 10 g/y, at one volcano assuming respective calcite‐free‐superliquidus conditions and a magma flux of 10 12 g/y). Our experimental results thus suggest that calcite assimilation in more mafic magmas may have first degassed a significant amount of crustal carbon before the melt evolves to more silicic compositions, producing skarn. Crustal decarbonation in long‐lived magmatic systems may hence deliver significant albeit diminishing amounts of carbon to the atmosphere and contribute to long‐term climate change. Key Points: Limestone assimilation increases with infiltration of hydrous andesitic melt over basaltic but decreases with dacite Skarn minerals like wollastonite increase in abundance in more silicic magma‐calcite interaction Assimilation can release <∼0.4 Gt CO2 during intruding magma evolution from basalt to granite