Rhodium(iii)-catalyzed ortho-alkenylation using a cyclic N-phosphoryl ketimine as the directing group. Issue 40 (26th September 2016)

• Record Type: Journal Article
• Authors: Zhu, Yu-Qin; Qin, Liu; Song, Qiang; Su, Fu; Xu, Yan-Jun; Dong, Lin
• Is Part Of: Organic & biomolecular chemistry. Volume 14:Issue 40(2016)
• Page Start: 9472
• Page End: 9475
• Publication Date: 2016-09-26
• Subjects: Chemistry, Organic -- Periodicals; Bioorganic chemistry -- Periodicals; Chemistry, Physical organic -- Periodicals; 547
• DOI: 10.1039/c6ob01899h
• Languages: English
• ISSNs: 1477-0520

Abstract

Abstract : A novel cyclic N -phosphoryl ketimine structure can efficiently react with olefins as useful directing groups to construct a myriad of phosphate scaffolds via rhodium(iii )-catalyzed ortho -alkenylation. Abstract : A novel cyclic N -phosphoryl ketimine structure can efficiently react with olefins as useful directing groups to construct a myriad of phosphate scaffolds via rhodium(iii )-catalyzed ortho -alkenylation. This method provides a probability that the coupling products could be used as a building block to access more complex organic phosphorus compounds.