Radical–radical cross coupling reactions of photo-excited fluorenones. Issue 40 (21st September 2016)

• Record Type: Journal Article
• Authors: Sharma, Simmi; Sultan, Shaista; Devari, Shekaraiah; Shah, Bhahwal Ali
• Is Part Of: Organic & biomolecular chemistry. Volume 14:Issue 40(2016)
• Page Start: 9645
• Page End: 9649
• Publication Date: 2016-09-21
• Subjects: Chemistry, Organic -- Periodicals; Bioorganic chemistry -- Periodicals; Chemistry, Physical organic -- Periodicals; 547
• DOI: 10.1039/c6ob01879c
• Languages: English
• ISSNs: 1477-0520

Abstract

Abstract : Radical–radical cross coupling reactions of photoexcited 9-fluorenones have been accomplished for the first time, leading to the synthesis of 9-alkyl, pyrollidinyl and spiro-THF derivatives of 9-fluorenones. Abstract : Radical–radical cross coupling reactions of photoexcited 9-fluorenones have been accomplished for the first time, leading to the synthesis of 9-alkyl, pyrollidinyl and spiro-THF derivatives of 9-fluorenones. The method also reveals, for the first time, the behaviour of ketyl radicals in decarboxyaltive alkylation and ring expansion reactions.