Palladium-catalyzed decarboxylative ortho-arylation of 2-pyridyl sulfoxides with benzoyl peroxides. Issue 45 (1st November 2016)

• Record Type: Journal Article
• Authors: Sun, Meng; Wang, Zhe; Wang, Jiaxin; Guo, Peiyu; Chen, Xiangxiang; Li, Ya-Min
• Is Part Of: Organic & biomolecular chemistry. Volume 14:Issue 45(2016)
• Page Start: 10585
• Page End: 10588
• Publication Date: 2016-11-01
• Subjects: Chemistry, Organic -- Periodicals; Bioorganic chemistry -- Periodicals; Chemistry, Physical organic -- Periodicals; 547
• DOI: 10.1039/c6ob02040b
• Languages: English
• ISSNs: 1477-0520

Abstract

Abstract : A palladium catalyzed efficient strategy for regio-selective ortho -arylation of sulfoxides with aryl acyl peroxides via decarboxylation has been developed. Abstract : A palladium catalyzed efficient strategy for regio-selective ortho -arylation of sulfoxides with benzoyl peroxides via decarboxylation has been developed. This reaction proceeds smoothly, tolerates a variety of functional groups, and provides easy access to the synthesis of different biaryl compounds.