Direct synthesis of non-breathing MIL-53(Al)(ht) from a terephthalate-based ionic liquid as linker precursor. Issue 46 (7th November 2016)

• Record Type: Journal Article
• Authors: Fischer, Marcus; Schwegler, Johannes; Paula, Carolin; Schulz, Peter S.; Hartmann, Martin
• Is Part Of: Dalton transactions. Volume 45:Issue 46(2016)
• Page Start: 18443
• Page End: 18446
• Publication Date: 2016-11-07
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c6dt03930h
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : An organic imidazolium salt of terephthalic acid has been utilized as a linker precursor for the synthesis of an aluminum-based metal organic framework (MOF) with MIL-53(ht) structure. Abstract : An organic imidazolium salt of terephthalic acid has been utilized as a linker precursor for the synthesis of an aluminum-based metal organic framework (MOF) with MIL-53(ht) structure. This material shows the predicted porosity in terms of nitrogen and hydrogen sorption without exhibiting the breathing effect typical for MIL-53(Al) materials.