Palladacycle catalysis: an innovation to the Suzuki–Miyaura cross-coupling reaction. Issue 44 (24th October 2016)

• Record Type: Journal Article
• Authors: Lucio-Martínez, Fátima; Adrio, Luis A.; Polo-Ces, Paula; Ortigueira, Juan M.; Fernández, Jesús J.; Adams, Harry; Pereira, M. Teresa; Vila, José M.
• Is Part Of: Dalton transactions. Volume 45:Issue 44(2016)
• Page Start: 17598
• Page End: 17601
• Publication Date: 2016-10-24
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c6dt03542f
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : A new approach to the Suzuki cross-coupling reaction based on the catalysis of a thiosemicarbazone palladacycle is presented. Abstract : Herein we report a Suzuki–Miyaura type cross-coupling between an aryl halide and a functionalized boronic acid palladacycle in the absence of an external catalyst. This reaction is an unprecedented case of catalysis in palladium metallacycle chemistry.