Dinuclear uranium complexation and manipulation using robust tetraaryloxides. Issue 40 (26th August 2016)

• Record Type: Journal Article
• Authors: Wells, Jordann A. L.; Seymour, Megan L.; Suvova, Markéta; Arnold, Polly L.
• Is Part Of: Dalton transactions. Volume 45:Issue 40(2016)
• Page Start: 16026
• Page End: 16032
• Publication Date: 2016-08-26
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c6dt02630c
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Two lower-oxidation state uranium cations can be readily combined and controlled in a robust and derivatisable tetra-aryloxide ligand framework. These di-U III/IV systems are a new platform at which to use the multi-electron reductive capacity of the two actinide centres. Abstract : Two lower-oxidation state uranium cations can be readily combined in a robust, yet flexible and derivatisable, tetraaryloxide ligand framework, affording a new platform at which to use the multi-electron reductive capacity of the two actinide centres.