Coexistence of self- and interpenetration in two (3, 6)-connected porous coordination polymers. Issue 44 (19th October 2016)

• Record Type: Journal Article
• Authors: Yao, Qingxia; Fan, Yerong; Wang, Zhan; Duan, Wenzeng; Wang, Suna; Li, Yunwu; Li, Dacheng; Zhang, Qingfu; Du, Yuchang; Dou, Jianmin
• Is Part Of: CrystEngComm. Volume 18:Issue 44(2016)
• Page Start: 8574
• Page End: 8577
• Publication Date: 2016-10-19
• Subjects: Crystals -- Periodicals; Crystal growth -- Periodicals; Crystallography -- Periodicals; Cristaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Cristallographie -- Périodiques; 548
• DOI: 10.1039/c6ce01705c
• Languages: English
• ISSNs: 1466-8033

Abstract

Abstract : Two self-penetrating coordination networks are mutually interpenetrated to give a soft porous entanglement, which can be used for the selective detection of nitrobenzene through fluorescence quenching. Abstract : Two isostructural (3, 6)-connected porous coordination polymers topologically featuring both self- and interpenetration have been successfully synthesized. The porous material shows a reversible crystalline-to-amorphous transition associated with the removal and recapture of guest molecules. Particularly, the porous material demonstrates selective detection of nitrobenzene through fluorescence quenching.