Photochemical CO2 reduction in water using a co-immobilised nickel catalyst and a visible light sensitiser. Issue 99 (28th November 2016)

• Record Type: Journal Article
• Authors: Neri, Gaia; Forster, Mark; Walsh, James J.; Robertson, C. M.; Whittles, T. J.; Farràs, Pau; Cowan, Alexander J.
• Is Part Of: Chemical communications. Volume 52:Issue 99(2016)
• Page Start: 14200
• Page End: 14203
• Publication Date: 2016-11-28
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c6cc08590c
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Dye-sensitised photocatalytic CO2 reduction in water using an immobilised Nickel catalyst operates with efficiencies greatly exceeding the equivalent solution based system. Abstract : A dye-sensitised CO2 reduction photocatalyst that operates in water is reported. Transient spectroscopy demonstrates that the facile co-immobilisation of a Ru dye and a Ni CO2 reduction electrocatalyst enables efficient on-particle electron transfer leading to photocatalytic activity that greatly exceeds the equivalent solution based system.