The palladium/norbornene-catalyzed ortho-silylmethylation reaction: a practical protocol for ortho-functionalized one-carbon homologation of aryl iodides. Issue 97 (17th November 2016)
- Record Type:
- Journal Article
- Title:
- The palladium/norbornene-catalyzed ortho-silylmethylation reaction: a practical protocol for ortho-functionalized one-carbon homologation of aryl iodides. Issue 97 (17th November 2016)
- Main Title:
- The palladium/norbornene-catalyzed ortho-silylmethylation reaction: a practical protocol for ortho-functionalized one-carbon homologation of aryl iodides
- Authors:
- Sui, Xianwei
Ding, Linlin
Gu, Zhenhua - Abstract:
- Abstract : We reported the introduction of a functionalized methyl group into the ortho -position using the Catellani reaction. Abstract : A palladium/norbornene-catalyzed ortho -silylmethylation reaction using of (iodomethyl)cyclohexyloxydimethylsilane as the electrophile was reported. The ((cyclohexyloxy)dimethylsilyl)methyl group was readily oxidized using the Fleming–Tamao process or by ceric ammonium nitrate to give benzylic alcohol derivatives. This method was successfully applied in a concise synthesis of a biaryl analogue of schisandrins.
- Is Part Of:
- Chemical communications. Volume 52:Issue 97(2016)
- Journal:
- Chemical communications
- Issue:
- Volume 52:Issue 97(2016)
- Issue Display:
- Volume 52, Issue 97 (2016)
- Year:
- 2016
- Volume:
- 52
- Issue:
- 97
- Issue Sort Value:
- 2016-0052-0097-0000
- Page Start:
- 13999
- Page End:
- 14002
- Publication Date:
- 2016-11-17
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c6cc08227k ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 453.xml