Oligo(aryl-triazole)s CH⋯Cl− interactions guide chloride efficient and selective transmembrane transport. Issue 89 (20th October 2016)

• Record Type: Journal Article
• Authors: Chen, Sujun; Zhang, Sitong; Bao, Chunyan; Wang, Chenxi; Lin, Qiuning; Zhu, Linyong
• Is Part Of: Chemical communications. Volume 52:Issue 89(2016)
• Page Start: 13132
• Page End: 13135
• Publication Date: 2016-10-20
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c6cc07792g
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Using specific C–H⋯Cl − interactions, oligo(aryl-triazole) based transporters realized efficient/selective Cl − transmembrane transport by adjusting their molecular lipophilicity and anion affinity. Abstract : A series of oligo(aryl-triazole)s (compounds1–8 ) have been synthesized and served as transmembrane anion transporters by only CH⋯Cl − interactions. This work confirms their role in the activity of anion transport. By changing the lipophilicity and anion affinity of the compounds, efficient anion transport with remarkable Cl − vs. HCO3 − selectivity was achieved.