Hierarchical silicalite-1 octahedra comprising highly-branched orthogonally-stacked nanoplates as efficient catalysts for vapor-phase Beckmann rearrangement. Issue 80 (16th September 2016)

• Record Type: Journal Article
• Authors: Chang, Albert; Hsiao, Hsu-Ming; Chen, Tsai-Hsiu; Chu, Ming-Wen; Yang, Chia-Min
• Is Part Of: Chemical communications. Volume 52:Issue 80(2016)
• Page Start: 11939
• Page End: 11942
• Publication Date: 2016-09-16
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c6cc05992a
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : A structure-directing agent was designed to synthesize hierarchical silicalite-1 octahedra comprising highly-branched and orthogonally-stacked nanoplates that exhibited excellent and stable activity for Beckmann rearrangement of cyclic oximes and high lactam selectivity. Abstract : A triblock structure-directing agent was designed to synthesize hierarchical silicalite-1 octahedra comprising highly-branched, orthogonally-stacked and self-pillared nanoplates that exhibited excellent and stable activity for the vapor-phase Beckmann rearrangement of cyclic oximes and high lactam selectivity.