ChemInform Abstract: {[CuSn5Sb3]2‐}2: A Dimer of Inhomogeneous Superatoms. Issue 48 (10th November 2016)

• Record Type: Journal Article
• Authors: Wilson, Robert J.; Broeckaert, Lies; Spitzer, Fabian; Weigend, Florian; Dehnen, Stefanie
• Is Part Of: ChemInform. Volume 47:Issue 48(2016)
• Page Start: no
• Page End: no
• Publication Date: 2016-11-10
• Subjects: copper, Cu -- tin, Sn -- antimony, Sb -- structure (solids and liquids); Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201648018
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: Crystals of [K([2.2.2]crypt)]4 [CuSn5 Sb3 ]2 ·3en (I) and [K([2.2.2]crypt)]4 [CuSn5 Sb3 ]2 ·2toluene (II) are obtained in the reaction of equimolar amounts [K([2.2.2]crypt)]2 [Sn2 Sb2 ]·en (III) and the β‐diketiminato complex [LCu(MeCN)] (L: [(N(C6 H3 iPr2 ‐2, 6)C(Me))2 CH] ‐ ) in en or DMF (3 h; layering with toluene, 5 °C, 10—14 d).